The extremely complex kinetics of pumping, quenching, and absorption in krypton fluoride excimer lasers is now relatively well understood. A single comprehensive kinetic model, solved approximately by analytic means and more exactly by a computer code of moderate size, is capable of simulating with great accuracy the performance of KrF lasers pumped by e‐beam sustained discharge, and self‐sustained discharge. We present the results of applications of this model to interpret and predict the limiting behavior and scaling of KrF lasers. A measure of remaining uncertainties is discussed.

1.
M. F.
Golde
,
J. Mol. Spectrosc.
58
,
261
(
1975
).
2.
J. E.
Velazco
and
D. W.
Setser
,
IEEE J. Quantum. Electron.
11
,
708
(
1975
).
3.
C. A.
Brau
and
J. J.
Ewing
,
J. Chem. Phys.
63
,
4640
(
1975
).
4.
J. J.
Ewing
and
C. A.
Brau
,
Appl. Phys. Lett.
27
,
350
(
1975
).
5.
J.
Tellinghuisen
,
Chem. Phys. Lett.
29
,
359
(
1974
);
Phys. Rev. Lett.
34
,
1137
(
1975
).
6.
J.
Tellinghuisen
,
A. K.
Hays
,
J. M.
Hoffman
, and
G. C.
Tisone
,
J. Chem. Phys.
65
,
4473
(
1975
).
7.
T. H.
Dunning
and
P. J.
Hay
,
Appl. Phys. Lett.
28
,
649
(
1976
);
T. H.
Dunning
and
P. J.
Hay
,
J. Chem. Phys.
69
,
134
(
1978
).
8.
A. E.
Greene
and
C. A.
Brau
,
IEEE J. Quantum Electron.
QE‐14
,
951
(
1978
).
9.
L. G.
Piper
,
J. E.
Velazco
, and
D. W.
Setser
,
J. Chem. Phys.
59
,
3323
(
1973
).
10.
D. G.
Sutton
,
S. N.
Suchard
,
O. L.
Gibb
, and
C. P.
Wang
,
Appl. Phys. Lett.
28
,
522
(
1976
).
11.
M. L.
Bhaumik
,
R. S.
Bradford
, Jr.
, and
E. R.
Ault
,
Appl. Phys. Lett.
28
,
23
(
1976
).
12.
M. J.
Shaw
and
J. D. C.
Jones
,
Appl. Phys.
14
,
393
(
1977
).
13.
M.
Rockni
,
J. A.
Mangano
,
J. H.
Jacob
, and
J. C.
Hsia
,
IEEE J. Quantum. Electron.
QE‐14
,
464
(
1978
).
14.
G. C.
Tisone
,
A. K.
Hayes
, and
J. M.
Hoffman
,
Opt. Commun.
15
,
188
(
1975
).
15.
R. O. Hunter, C. Howton, and J. Oldenettel, AIAA 15th Aerospace Sciences Meeting, Paper 77‐26 (unpublished).
16.
J. A.
Mangano
and
J. H.
Jacob
,
Appl. Phys. Lett.
27
,
495
(
1975
).
17.
L. R.
Peterson
and
J. E.
Allen
, Jr.
,
J. Chem. Phys.
56
,
6068
(
1972
).
18.
J. H.
Jacob
and
J. A.
Mangano
,
Appl. Phys. Lett.
28
,
724
(
1976
).
19.
J. D.
Daugherty
,
J. A.
Mangano
, and
J. H.
Jacob
,
Appl. Phys. Lett.
28
,
581
(
1976
).
20.
R. O. Hunter (unpublished).
21.
J. Mangano (unpublished).
22.
J. H.
Jacob
and
J. A.
Mangano
,
Appl. Phys. Lett.
29
,
467
(
1976
).
23.
W. R.
Wadt
,
D. C.
Cartwright
, and
J. S.
Cohen
,
Appl. Phys. Lett.
31
,
672
(
1977
).
24.
H. H. Michels, R. H. Hobbs, and L. A. Wright, Int. J. Quantum Chem. (1978).
25.
R. O. Hunter and M. McCusker (unpublished).
26.
E.
Eggarter
,
J. Chem. Phys.
62
,
833
(
1975
).
27.
P. S.
Ganas
and
A. E. S.
Green
,
Phys. Rev. A
4
,
182
(
1971
).
28.
M.
Shaper
and
H.
Scheibner
,
Bett. Plasma. Phys.
9
,
45
(
1969
).
29.
D.
Rapp
and
P.
Englander‐Golden
,
J. Chem. Phys.
43
,
1464
(
1965
).
30.
E. W. McDaniel, V. Ermak, A. Dalgarno, E. E. Ferguson, and L. Friedman, Ion Molecule Reaction (Wiley‐Interscience, New York, 1970).
31.
D. K.
Bohme
,
N. G.
Adams
,
M.
Muselman
,
D. B.
Donkin
, and
E. E.
Ferguson
,
J. Chem. Phys.
52
,
5094
(
1970
).
A measurement of a considerably different (103 smaller) value of this rate constant than that estimated in this reference (as used in the code reported here) is reported by
R.
Johnsen
,
J.
MacDonald
, and
M. A.
Biondi
[
J. Chem. Phys.
68
,
2991
(
1978
)].
32.
J. A.
Mangano
,
J. H.
Jacob
,
M.
Rokni
, and
A.
Hawryluk
,
Appl. Phys. Lett.
31
,
26
(
1977
).
33.
H. H. Nakano, R. M. Hill, D. C. Lorents, D. L. Huestis, and M. V. McCusker, SRI Report MP‐76‐99, 1976.
34.
J. N.
Bardsley
and
M. A.
Biondi
,
Adv. At. Mol. Phys.
6
(
1970
).
35.
K. J.
McCann
and
M. R.
Flannery
,
Appl. Phys. Lett.
31
,
599
(
1977
).
36.
H. A.
Hyman
,
Appl. Phys. Lett.
31
,
14
(
1977
).
37.
L.
Vriens
,
Physica
31
,
395
(
1965
).
38.
V. H.
Shui
,
Appl. Phys. Lett.
31
,
50
(
1977
).
39.
W. B.
Lacina
and
D. B.
Cohn
,
Appl. Phys. Lett.
32
,
106
(
1978
).
40.
J. H.
Jacob
,
M.
Rokni
,
J. A.
Mangano
, and
R.
Brochu
,
Appl. Phys. Lett.
32
,
109
(
1978
).
41.
H.
Chen
,
R. E.
Center
,
D. W.
Trainor
, and
W. I.
Fyfe
,
Appl. Phys. Lett.
30
,
99
(
1977
).
42.
J. G. Calvert and J. N. Pitts, Photochemistry (Wiley, New York, 1966).
43.
W. R.
Wadt
,
D. C.
Cartwright
,
J. S.
Cohen
,
Appl. Phys. Lett.
31
,
672
(
1977
).
44.
J. N.
Bardsley
,
Appl. Phys. Lett.
32
,
76
(
1978
).
45.
C. J.
Chea
,
Phys. Rev.
177
,
245
(
1969
).
46.
M. A.
Biondi
,
Phys. Rev.
129
,
1181
(
1963
).
47.
A.
Mandl
,
Phys. Rev. A
3
,
251
(
1971
).
48.
Estimated by H. Michels (United Technology Research Center) and L. Wright (Air Force Weapons Laboratory).
49.
T. H.
Johnson
,
L.
Palumbo
, and
A. M.
Hunter
,
IEEE J. Quantum Electron
QE‐15
,
289
(
1979
).
50.
R. O. Hunter, C. Howton, and J. Oldenettel, AIAA 15th Aerospace Sciences Meeting, Paper 77‐26.
51.
M. J. Berger and S. M. Seltzer, NAS‐NRC Publication 1133, pp. 205–268, 1965 (unpublished).
52.
R. O. Hunter (private communication).
53.
A. M.
Hunter
and
T. H.
Johnson
,
Bull. Am. Phys. Soc.
22
,
1041
(
1977
).
54.
W. H.
Long
, Jr.
,
Appl. Phys. Lett.
31
,
391
(
1977
).
55.
W. L.
Nighan
,
IEEE J. Quantum Electron.
QE‐14
,
714
(
1978
).
56.
C. P. Holmes, A. M. Hunter, E. J. Jumper, and R. D. Franklin (unpublished).
57.
D. Cohn (unpublished).
58.
D. E. Phelps, R. Baumgardner, and G. H. Canavan, AIAA Paper 74–181, 1974 (unpublished).
59.
E. A.
Sziklas
and
A. E.
Siegman
,
Appl. Opt.
14
,
1874
(
1975
).
60.
T. C. Salvi, Laser Digest, AFWL‐TR‐74‐344 (Air Force Weapons Laboratory, Kirtland AFB, 1975), p. 71.
61.
J. R. Murray and J. Goldhar, Tenth International Quantum Electronics Conference, 1978, Paper U.8 (unpublished).
62.
D. C. Lorents, in Electronic and Atomic Collisions, edited by G. Watel (North‐Holland, Amsterdam, 1978).
63.
J. J.
Lowke
,
A. V.
Phelps
, and
B. W.
Irwin
,
J. Appl. Phys.
44
,
4464
(
1973
).
64.
I. P. Shkarofsky, T. W. Johnston, and M. P. Bachynski, The Particle Kinetics of Plasmas (Addison‐Wesley, London, 1966), p. 284.
65.
R. O. Hunter, Jr. (private communication). This experiment has been run in self‐sustained mode unintentionally, continuing to lase after the e‐beam was turned off.
66.
D. C.
Lorents
,
Physica,
82C
,
19
(
1976
).
67.
J. H.
Jacob
,
J. Appl. Phys.
45
,
467
(
1974
).
68.
T. C. Salvi (private communication).
69.
Intrinsic efficiency should not be confused with the discharge production efficiency as used, for example, in Ref. 55. Intrinsic efficiency includes both KrF* production and energy extraction efficiencies. For that reason it is a more realistic estimate of actual laser operation efficiency, and it can be compared directly with experiments.
70.
A. M.
Hawryluk
,
J. A.
Mangano
, and
J. H.
Jacob
,
Appl. Phys. Lett.
31
,
164
(
1977
).
This content is only available via PDF.
You do not currently have access to this content.