Jump to content

Arsenidogermanate

From Wikipedia, the free encyclopedia

Arsenidogermanates are chemical compounds that contain anions with arsenic bonded to germanium. They are in the category of tetrelarsenides, pnictidogermanates, or tetrelpnictides.

Germanium forms two arsenides: GeAs and GeAs2.[1]

List

[edit]
name formula formula

weight

crystal

system

space

group

unit cell volume density comments ref
LiGe3As3 orthorhombic Pbam a=10.0862 b=15.7612 c=3.7403 Z=4 594.60 5.01 [2]
Li5GeAs3 black [3]
NaGe6As6 908.05 monoclinic C2/m a = 22.063, b = 3.8032, c = 7.2020, β = 92.744°, Z = 2 603.64 5.00 needles [4]
Na10Ge2As6 monoclinic P121/n1 a=13.531 b=7.544 c=8.298 β = 90.2° Z=2 847.0 [5]
K2GeAs2 orthorhombic Ibam a = 13.292, b = 7.028, c = 6.548 Z = 4 moisture sensitive needles [6]
KGe3As3 481.53 orthorhombic Pnma a=9.993, b=3.7664, c=18.607 Z=4 700.34 4.568 [7]
K2Ge3As3 520.73 orthorhombic Pnnm a=14.1466 b=16.300 c=3.7489 Z=4 864.47 4.001 fibrous metallic [8]
K2NaGaAs2 Ibam a=6.733 b=14.809 c=6.574 Z=4 655.5 3.250 [9]
KCdGeAs2 triclinic P1 a = 8.004, b = 8.402, c = 8.703, α = 71.019°, β = 75.257°, γ = 73.746°, Z=4 band gap 0.8 eV; Ge2As6 units [10]
RbCdGeAs2 triclinic P1 a = 8.269, b = 8.452, c = 8.735, α = 71.163°, β = 75.601°, γ = 73.673°, Z=4 Ge2As6 units [10]
Sr3Ge2As4 red metallic; 1D As3GeGeAs3 units [11]
K5In5Ge5As14 monoclinic C2/m a=40.00,b=3.925,c=10.299, β=99.97°, Z=8 1592 4.55 air sensitive; layered [12]
K8In8Ge5As17 monoclinic P21/c a=18.394,b=19.087,c=25.360, β=105.71°, Z=4 8571 4.45 air sensitive; layered [12]
RbGe3As3 528 orthorhombic Pnma a=10.166 b=3.7595 c=19.028 Z=4 727.2 4.823 [7]
Rb(Ge1.5In0.5)As2(As1.5Ge0.5) orthorhombic Cmc21 a = 3.799, b = 16.50, c = 12.24, Z = 4 767 4.589 [13]
RbXGe2−XInXAs4 [13]
I8As21Ge25 4403 cubic Pm3n a=10.5963 Z=1 1189.8 6.1431 colourless [14]
Cs5GeAs3 metallic; unstable in air; GeAs3 units [15]
BaGe2As2 tetragonal P42mc a=7,786 c=8.664 Z=4 525.2 5.47 metallic [16]
Ba4GeAs4 dark metallic; GeAs4 units [17]
Re3Ge0.6As6.4 [18]
Re3GeAs6 1080.75 cubic Im3m a = 8.73202 Z=4 665.75 10.78 n-type semiconductor [18]
AuGeAs monoclinic Cc a 7.2729, b 6.2953, c 6.3067, β 119.209° [19]
KXGe2−XTlXAs4 [13]

References

[edit]
  1. ^ Stöhr, Herbert; Klemm, Wilhelm (1940-07-09). "Über Zweistoffsysteme mit Germanium. II. Germanium/Arsen, Germanium/Antimon, Germanium/Wismut". Zeitschrift für anorganische und allgemeine Chemie. 244 (2): 205–223. doi:10.1002/zaac.19402440211.
  2. ^ Mark, Justin; Hanrahan, Michael P.; Woo, Katherine E.; Lee, Shannon; Rossini, Aaron J.; Kovnir, Kirill (2 May 2019). "Chemical and Electrochemical Lithiation of van der Waals Tetrel‐Arsenides". Chemistry – A European Journal. 25 (25): 6392–6401. doi:10.1002/chem.201900339. OSTI 1526289. PMID 30887569. S2CID 83463348.
  3. ^ Juza, Robert; Schulz, Werner (February 1954). "Ternäre Phosphide und Arsenide des Lithiums mit Elementen der 3. und 4. Gruppe". Zeitschrift für anorganische und allgemeine Chemie (in German). 275 (1–3): 65–78. doi:10.1002/zaac.19542750107. ISSN 0044-2313.
  4. ^ Khatun, Mansura; Mar, Arthur (2016-05-01). "NaGe6As6: Insertion of sodium into the layered semiconductor germanium arsenide GeAs". Zeitschrift für Naturforschung B. 71 (5): 375–380. doi:10.1515/znb-2015-0203. ISSN 1865-7117. S2CID 197298002.
  5. ^ Eisenmann, B.; Klein, J.; Somer, M. (1991-02-01). Eisenmann, B.; Klein, J.; Somer, M. (eds.). "Crystal structure of decasodium di-μ-arsenido-bis(diarsenidogermanate), Na10Ge2As6". Zeitschrift für Kristallographie - Crystalline Materials. 197 (3–4): 265–266. Bibcode:1991ZK....197..265E. doi:10.1524/zkri.1991.197.3-4.265. ISSN 2194-4946.
  6. ^ Eisenmann, Brigitte; Klein, Jürgen (September 1991). "SiS2-isostrukturelle Anionen [SiP22−], [GeAs22−] und [SnAs22−] in Alkaliverbindungen". Journal of the Less Common Metals (in German). 175 (1): 109–117. doi:10.1016/0022-5088(91)90355-8.
  7. ^ a b Khatun, Mansura; Stoyko, Stanislav S.; Mar, Arthur (June 2016). "Ternary arsenides ATt3As3 (A=K, Rb; Tt=Ge, Sn) with layered structures". Journal of Solid State Chemistry. 238: 229–235. Bibcode:2016JSSCh.238..229K. doi:10.1016/j.jssc.2016.03.035.
  8. ^ Eulenstein, Armin R.; Bogdanovski, Dimitri; Reinhardt, Hendrik; Miß, Vanessa; Roling, Bernhard; Hampp, Norbert; Dronskowski, Richard; Dehnen, Stefanie (12 November 2019). "K2Ge3As3: Fiberlike Crystals of a Narrow-Band-Gap Zintl Phase with a One-Dimensional Substructure 1{(Ge3As3)2–}". Chemistry of Materials. 31 (21): 8839–8849. doi:10.1021/acs.chemmater.9b02827. S2CID 204116281.
  9. ^ Somer, Mehmet; Peters, Karl; von Schnering, Hans Georg (July 1992). "K2NaGaP2, Cs2NaGaP2, K2NaGaAs2, K2NaInP2 und K2NaInAs2, Verbindungen mit den SiS2-isosteren Polyanionen
    1
    [MX4/2]3− (M=Ga, In; X=P, As)"
    . Zeitschrift für anorganische und allgemeine Chemie (in German). 613 (7): 19–25. doi:10.1002/zaac.19926130103. ISSN 0044-2313.
  10. ^ a b Khatun, Mansura; Stoyko, Stanislav S.; Mar, Arthur (21 July 2014). "Quaternary Arsenides ACdGeAs2 (A = K, Rb) Built of Ethane-Like Ge2As6 Units". Inorganic Chemistry. 53 (14): 7756–7762. doi:10.1021/ic5011264. PMID 24983676.
  11. ^ Eisenmann, Brigitte; Schäfer, Herbert (June 1980). "Zintl Phases with Complex Anions: Sr3Si2As4 and Sr3Ge2As4". Angewandte Chemie International Edition in English. 19 (6): 490–491. doi:10.1002/anie.198004901.
  12. ^ a b Shreeve-Keyer, Julie L; Haushalter, Robert C; Lee, Young-Sook; Li, Sichu; O'Connor, Charles J; Seo, Dong-Kyun; Whangbo, Myung-Hwan (May 1997). "New Layered Materials in the K–In–Ge–As System: K8In8Ge5As17 and K5In5Ge5As14". Journal of Solid State Chemistry. 130 (2): 234–249. Bibcode:1997JSSCh.130..234S. doi:10.1006/jssc.1996.7210.
  13. ^ a b c Shreeve-Keyer, Julie L.; Haushalter, Robert C. (1996), Kajimura, Koji; Kuroda, Shin-ichi (eds.), "Synthesis and Structural Characterization of a Quaternary Zintl Phase Material from the Rb:Ge:In:As System: Rb(Ge1.5ln0.5)As2(As1.5Ge0.5)", Materials and Measurements in Molecular Electronics, Springer Proceedings in Physics, vol. 81, Tokyo: Springer Japan, pp. 139–150, doi:10.1007/978-4-431-68470-1_11, ISBN 978-4-431-68472-5, retrieved 2021-12-08
  14. ^ Ayouz, Katia; Kars, Mohammed; Rebbah, Allaoua; Rebbah, Houria (15 March 2009). "I8As21Ge25". Acta Crystallographica Section E. 65 (3): i15. doi:10.1107/S1600536809004991. PMC 2968696. PMID 21582033.
  15. ^ Eisenmann, Brigitte; Klein, Jürgen; Somer, Mehmet (January 1990). "Anions Isosteric with CO32− in Cs5SiP3, Cs5SiAs3, Cs5GeP3, and Cs5GeAs3". Angewandte Chemie International Edition in English. 29 (1): 87–88. doi:10.1002/anie.199000871.
  16. ^ Eisenmann, Brigitte; Schäfer, Herbert (1981-04-01). "Zintlphasen mit binären Anionen: Zur Kenntnis von BaGe2P2 und BaGe2As2 / Zintl Phases with Binary Anions: BaGe2P2 and BaGe2As2". Zeitschrift für Naturforschung B. 36 (4): 415–419. doi:10.1515/znb-1981-0403. ISSN 1865-7117. S2CID 95993285.
  17. ^ Eisenmann, Brigitte; Jordan, Hanna; Schäfer, Herbert (February 1981). "Ba4SiAs4, and Ba4GeAs4, Zintl Phases with Isolated SiAs48− and GeAs48− anions". Angewandte Chemie International Edition in English. 20 (2): 197–198. doi:10.1002/anie.198101972.
  18. ^ a b Soheilnia, Navid; Xu, Hong; Zhang, Huqin; Tritt, Terry M.; Swainson, Ian; Kleinke, Holger (1 August 2007). "Thermoelectric Properties of Re3Ge0.6As6.4 and Re3GeAs6 in Comparison to Mo3Sb5.4Te1.6". Chemistry of Materials. 19 (16): 4063–4068. doi:10.1021/cm0708517.
  19. ^ Lee, Shannon J.; Won, Juyeon; Wang, Lin‐Lin; Jing, Dapeng; Harmer, Colin P.; Mark, Justin; Akopov, Georgiy; Kovnir, Kirill (6 May 2021). "New Noncentrosymmetric Tetrel Pnictides Composed of Square‐Planar Gold(I) with Peculiar Bonding". Chemistry – A European Journal. 27 (26): 7383–7390. doi:10.1002/chem.202005312. PMC 8251799. PMID 33523500.