Jump to content

Arsenide bromide

From Wikipedia, the free encyclopedia

Arsenide bromides or bromide arsenides are compounds containing anions composed of bromide (Br) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide iodides, phosphide bromides, and antimonide bromides.

List

[edit]
formula system space group unit cell Å volume density comment ref
(Ca2−xx)(As1−xBr1+x) Ca2AsBr cubic a=6.05 3.47 yellow, or dark brown [1][2]
Ca3AsBr3 cubic Pm3 a=5.91 3.48 colourless or yellow [1][2]
Cu6AsS5Br cubic F43m a=9.8763 4.80 [3][4]
(Ge38As8)+8⋅8 I cubic Pm3n a=10.625 5.71 semiconductor resistivity 1 Ω cm; band gap 0.9 eV; silvery grey [5]
I8As21Ge25 cubic Pm3n a=10.5963 Z=1 1189.77 6.143 colourless [6]
Cd2As3Br monoclinic C2/c a = 8.281, b = 9.411, c = 7.993, β = 101.49°, z = 4 5.76 black [7][8]
Cd4As2Br3 cubic Pa3 a=12.61 5.51 semiconductor band gap 1.8 eV [9]
Cd4PAsBr3 cubic Pa3 a=12.521 5.38 [10][4]
Cd4As2I1.5Br1.5 cubic Pa3 a=12.83 [11][4]
La3AsBr3 cubic I4132 a=12.09 5.50 [12]
Pr3AsBr3 cubic I4132 a=12.02 5.64 [12]
Hg2As3Br monoclinic C2/c a = 8.0914, b = 9.300, c = 8.1084, β = 99.323°, z = 4 7.79 black [7]
Hg4As2Br3 cubic Pa3 a=12.610 Z=8 2012.4 5.54 7.90 red; dark grey [13][14]
Hg19As10Br18 triclinic P1 a = 11.262, b = 11.352, c = 12.309, α = 105.724, β = 105.788, γ = 109.078° 1314.3 dark brown [15]
(HgBr2)3(As4S4)2 monoclinic P21/c a = 9.593, b = 11.395, c = 13.402, β = 107.27, Z = 2 1399 [16]
Hg3AsS4Br hexagonal P63mc a = 7.430, c = 9.364 Z=2 [17]
(Hg6As4)[TiBr6]Br cubic Pa3 a= 1230.9 [18]
[Hg6As4](CrBr6)Br cubic Pa a=12.275 [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV [19]
[Hg6As4](FeBr6)Hg0.6 cubic Pa a=12.332 [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV [19]
[Hg6As4](CuBr3)2 monoclinic I2/a a = 14.884, b = 9.358, c = 20.413, β=92.88°, Z = 6 dark red [20]
[Hg11As4](GaBr4)4 monoclinic C2/m [21]
Hg3AsSe4Br hexagonal P63mc a = 7.707, c = 9.47 Z=2 [17]
(Hg2Cd2As2Br)Br orthorhombic Pmma a = 8.791, b = 4.701, c = 9.779, Z=2 404.2 7.688 dark red [22]
(Hg6As4)(CdBr6) cubic Pa3 a=12.3738 Z=4 1894.6 7.345 red; air stable; band gap 1.94 [23]
[Hg6As4][InBr6]Br cubic Pa3 a=12.3511 Z=4 1884.2 dark red [24]
[Hg4As2](InBr3.5As0.5) Hexagonal P63/mmc a = 7.7408, c = 12.535, Z=2 650.47 [25]
[Hg6As4Br3](SnBr3) cubic P213 a=12.383 Z=4 [26]
[Hg6As4][YbBr6]Br cubic Pa3 a=12.362 Z=4 1889.1 7.860 dark red [27]
Hg9As4Bi2Br12 tetragonal P43 a=10.865 b=10.865 c=28.357 Z=4 3347.5 6.91 orange [28]

References

[edit]
  1. ^ a b Hadenfeldt, C.; Schulz, P. (November 1984). "Darstellung, Struktur und Temperaturabhängigkeit der Phasenbreite der Phase Ca2-xAs1-xBr1+x und thermisches Verhalten der Verbindung Ca3AsBr3". Zeitschrift für anorganische und allgemeine Chemie (in German). 518 (11): 77–86. doi:10.1002/zaac.19845181108. ISSN 0044-2313.
  2. ^ a b Hadenfeldt, Claus (1976-04-01). "Darstellung und Eigenschaften von Ca 2 AsBr, Sr 2 AsCl und Ca 3 AsBr 3 .: Preparation and Properties of Ca 2 AsBr, Sr 2 AsCl, and Ca 3 AsBr 3". Zeitschrift für Naturforschung B. 31 (4): 408–410. doi:10.1515/znb-1976-0403. ISSN 1865-7117. S2CID 95122668.
  3. ^ Nilges, Tom; Pfitzner, Arno (2005-03-01). "A structural differentiation of quaternary copper argyrodites: Structure — property relations of high temperature ion conductors". Zeitschrift für Kristallographie - Crystalline Materials. 220 (2–3): 281–294. Bibcode:2005ZK....220..281N. doi:10.1524/zkri.220.2.281.59142. ISSN 2196-7105. S2CID 56213950.
  4. ^ a b c Handbook of Inorganic Compounds 2015. 2015. p. 826.
  5. ^ Chu, T. L.; Chu, Shirley S.; Ray, R. L. (October 1982). "Germanium arsenide iodide: A clathrate semiconductor". Journal of Applied Physics. 53 (10): 7102–7103. Bibcode:1982JAP....53.7102C. doi:10.1063/1.330019. ISSN 0021-8979.
  6. ^ Ayouz, Katia; Kars, Mohammed; Rebbah, Allaoua; Rebbah, Houria (2009-03-15). "I 8 As 21 Ge 25". Acta Crystallographica Section E. 65 (3): i15. Bibcode:2009AcCrE..65I..15A. doi:10.1107/S1600536809004991. ISSN 1600-5368. PMC 2968696. PMID 21582033.
  7. ^ a b Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (November 1994). "A Novel Metallic Halide, Hg2As3Br: Synthesis and Crystal Structure, and Crystal Structure of Cd2As3Br". Journal of Solid State Chemistry. 113 (1): 116–119. Bibcode:1994JSSCh.113..116S. doi:10.1006/jssc.1994.1348.
  8. ^ Breitinger, Dietrich; Herrmann, Wolfgang A.; Hiller, Wolfgang (2014-05-14). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 5, 1999: Volume 5: Copper, Silver, Gold, Zinc, Cadmium and Mercury. Georg Thieme Verlag. p. 178. ISBN 978-3-13-179211-2.
  9. ^ Roy, Anand; Suchitra; Manjunath, K.; Ahmad, Tokeer; Waghmare, Umesh V.; Rao, C.N.R. (April 2017). "Electronic structure and properties of Cd 4 As 2 Br 3 and Cd 4 Sb 2 I 3 , analogues of CdSe and CdTe". Solid State Communications. 255–256: 5–10. Bibcode:2017SSCom.255....5R. doi:10.1016/j.ssc.2017.03.001.
  10. ^ REBBAH, A; A, DESCHANVRES (1981). "STRUCTURE CRISTALLINE DE Cd4PAsBr3". Ann. Chim. 6 (7): 585–590.
  11. ^ GAM, NS (1988). "PRODUCTION AND PROPERTIES OF CRYSTALS OF Cd4As2BrXI3-X SOLID-SOLUTIONS". Inorganic Materials. 24 (9): 1348–1350.
  12. ^ a b Handbook of Inorganic Substances 2015. 2015. p. 245.
  13. ^ Shevelkov, Andrei V.; Dikarev, Evgeny V.; Popovkin, Boris A. (November 1996). "Two New Cubic Structures of Mercury Arsenidehalides". Journal of Solid State Chemistry. 126 (2): 324–327. Bibcode:1996JSSCh.126..324S. doi:10.1006/jssc.1996.0344.
  14. ^ Kars, Mohammed; Roisnel, Thierry; Dorcet, Vincent; Rebbah, Allaoua; Otero-Diáz, L. Carlos (2014-03-01). "Cd 4 As 2 Br 3". Acta Crystallographica Section E. 70 (3): i15. Bibcode:2014AcCrE..70I..15K. doi:10.1107/S160053681400395X. ISSN 1600-5368. PMC 3998459. PMID 24764933.
  15. ^ "Synthesis, crystal and band structures, and optical properties of mercury pnictide halide Hg19As10Br18". Chinese Journal of Structural Chemistry. 30 (12): 1827–1832. 15 December 2011.
  16. ^ Bräu, Michael F.; Pfitzner, Arno (June 2007). "(HgBr2)3(As4S4)2: An Adduct of HgBr2 Molecules and Undistorted As4S4 Cages". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (7): 935–937. doi:10.1002/zaac.200600363.
  17. ^ a b Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01). "Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure". Inorganic Chemistry. 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388.
  18. ^ Beck, Johannes; Neisel, Udo (2000). "Synthese, Kristallstrukturen und Magnetismus von (Hg6As4)[MoCl6]Cl, (Hg6As4)[TiCl6]Cl und (Hg6As4)[TiBr6]Br". Zeitschrift für Anorganische und Allgemeine Chemie. 626 (7): 1620–1626. doi:10.1002/1521-3749(200007)626:7<1620::AID-ZAAC1620>3.0.CO;2-R.
  19. ^ a b Olenev, Andrei V.; Oleneva, Olga S.; Lindsjö, Martin; Kloo, Lars A.; Shevelkov, Andrei V. (2003-07-21). "Coordinated and Clathrated Guests in the [Hg6As4]4+ Bicompartmental Framework: Synthesis, Crystal and Electronic Structure, and Properties of the Novel Supramolecular Complexes [Hg6As4](CrBr6)Br and [Hg6As4](FeBr6)Hg0.6". Chemistry - A European Journal. 9 (14): 3201–3208. doi:10.1002/chem.200204687. PMID 12866063.
  20. ^ Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (June 2005). "Solid State Supramolecular Complexes [Hg6As4](CuX3)2 (X = Cl, Br): One-Dimensional Helical Guest in a Three-Dimensional Host Framework". Journal of Cluster Science. 16 (2): 273–285. doi:10.1007/s10876-005-4548-y. ISSN 1040-7278. S2CID 95453360.
  21. ^ Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020). "Crystallographic Analysis and Symmetry Generation for Some Structures with [As2] and [Hgn] (n = 2, 3) Cluster Groups". Journal of Structural Chemistry. 61 (2): 259–266. doi:10.1134/S0022476620020109. ISSN 0022-4766. S2CID 220540955.
  22. ^ Zou, Jian-Ping; Guo; Chen, Wen-Tong; Liu, Xi; Fu, Ming-Lai; Zhang; Huang, Jin-Shun (2006-08-01). "Synthesis, Crystal and Band Structures, and Optical Properties of a New Quaternary Metal Pnictidehalide: (Hg 2 Cd 2 As 2 Br)Br". Inorganic Chemistry. 45 (16): 6365–6369. doi:10.1021/ic060503r. ISSN 0020-1669. PMID 16878947.
  23. ^ Zou, Jian-Ping; Li, Yan; Fu, Ming-Lai; Guo, Guo-Cong; Xu, Gang; Liu, Xue-Hui; Zhou, Wei-Wei; Huang, Jin-Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 ](MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)". European Journal of Inorganic Chemistry. 2007 (7): 977–984. doi:10.1002/ejic.200600894. ISSN 1434-1948.
  24. ^ Deiseroth, Hans-Jörg; Schlirf, Jens; Reiner, Christof (June 2009). "Crystal structure of tetraarsenidohexamercury hexabromoindate bromide, [Hg6As4][InBr6]Br and tetraantimonidohexamercury hexabromoindate bromide, [Hg6Sb4][InBr6]Br". Zeitschrift für Kristallographie - New Crystal Structures. 224 (2): 167–168. doi:10.1524/ncrs.2009.0075. S2CID 201061929.
  25. ^ Zou, Jian-Ping; Luo, Sheng-Lian; Tang, Xing-Hua; Li, Ming-Jun; Zhang, Ai-Qin; Peng, Qiang; Guo, Guo-Cong (January 2011). "Synthesis, crystal and band structures, and optical properties of a new framework mercury pnictides: [Hg4As2](InBr3.5As0.5) with tridymite topology". Journal of Alloys and Compounds. 509 (2): 221–225. doi:10.1016/j.jallcom.2010.09.035.
  26. ^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.
  27. ^ Olenev, Andrei V.; Shestimerova, Tatiana A.; Schnelle, Walter; Shevelkov, Andrei V. (July 2005). "Synthesis, Structure, and Properties of [Hg6As4][YbBr6]Br, a Supramolecular Assembly Featuring a Discrete [YbBr6]3− Anion". Zeitschrift für anorganische und allgemeine Chemie (in German). 631 (9): 1698–1701. doi:10.1002/zaac.200500059. ISSN 0044-2313.
  28. ^ Puff, H.; Grönke, M.; Kilger, B.; Möltgen, P. (November 1984). "Darstellung und Struktur des Mercuroarsoniumbromo-bismutats [Hg7(HgBr)2As4] [Bi2Br10]". Zeitschrift für anorganische und allgemeine Chemie (in German). 518 (11): 120–128. doi:10.1002/zaac.19845181112. ISSN 0044-2313.