Bis(acetonitrile)palladium dichloride
Appearance
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Names | |
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Other names
palladium dichloride bis(acetonitrile), bis(acetonitrile)dichloropalladium
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Identifiers | |
3D model (JSmol)
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ECHA InfoCard | 100.035.110 |
EC Number |
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
C4H6Cl2N2Pd | |
Molar mass | 259.43 g·mol−1 |
Appearance | yellow-brown |
Melting point | 129–131 °C (264–268 °F; 402–404 K) |
Hazards | |
GHS labelling: | |
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Danger | |
H301, H311, H330 | |
P260, P261, P264, P270, P271, P273, P280, P284, P301+P310, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P310, P311, P312, P320, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P403+P233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Bis(acetonitrile)palladium dichloride is the coordination complex with the formula PdCl2(NCCH3)2. It is the adduct of two acetonitrile ligands with palladium(II) chloride. It is a yellow-brown solid that is soluble in organic solvents. The compound is a reagent and a catalyst for reactions that require soluble Pd(II).[1] The compound is similar to bis(benzonitrile)palladium dichloride. It reacts with 1,5-cyclooctadiene to give dichloro(1,5-cyclooctadiene)palladium.
References
[edit]- ^ Carretero, Juan Carlos; Arrayas, Ramon Gomez (2008). "Dichloro bis(acetonitrile) palladium". e-EROS Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rn00908. ISBN 978-0471936237.