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Silver bromate

From Wikipedia, the free encyclopedia
Silver bromate
Names
Systematic IUPAC name
Silver(I) bromate
Other names
Argentous bromate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.120 Edit this at Wikidata
  • InChI=1S/Ag.BrHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1 checkY
    Key: XQLMNMQWVCXIKR-UHFFFAOYSA-M checkY
  • InChI=1/Ag.BrHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1
    Key: XQLMNMQWVCXIKR-REWHXWOFAZ
  • [Ag+].[O-]Br(=O)=O
Properties
AgBrO3
Molar mass 235.770 g/mol
Appearance white powder
photosensitive
Density 5.206 g/cm3
Melting point 309 °C (588 °F; 582 K)
0.167 g/100 mL
5.38×10−5[1]
Solubility in ammonium hydroxide soluble
Hazards
GHS labelling:
GHS03: Oxidizing GHS07: Exclamation mark
Danger
H272, H315, H319, H335
P210, P220, P261, P264, P271, P280, P302+P352, P304+P340+P312, P305+P351+P338, P332+P313, P337+P313, P362+P364, P370+P378, P403+P233, P405, P501
Safety data sheet (SDS) MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Silver bromide GIF

Silver bromate (AgBrO3), is a toxic, light and heat-sensitive, white powder.[2]

Uses

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Silver bromate can be used as an oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds.[3]

References

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  1. ^ John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 978-1138561632.
  2. ^ Perry, Dale L. (2011). Handbook of inorganic compounds (2nd ed.). Boca Raton: Taylor & Francis. p. 365. ISBN 978-1-4398-1461-1. OCLC 587104373.
  3. ^ Mohammadpoor-Baltork, Iraj; Nourozi, Ali Reza (1999). "Efficient and Selective Oxidative Deprotection of Tetrahydropyranyl Ethers, Ethylene Acetals and Ketals with Silver and Sodium Bromates in the Presence of Aluminum Chloride". Synthesis. 1999 (3): 487–490. doi:10.1055/s-1999-3410. S2CID 196725503.
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